Delta H Solution Equation:
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Delta H solution (ΔH_sol) represents the enthalpy change when one mole of a substance dissolves in a solvent. It is calculated as the sum of lattice energy (ΔH_lattice) and hydration energy (ΔH_hydration).
The calculator uses the Delta H solution equation:
Where:
Explanation: The lattice energy is the energy required to break the crystal lattice, while hydration energy is the energy released when ions are surrounded by water molecules.
Details: Calculating ΔH_sol helps predict whether a dissolution process will be exothermic or endothermic, which is crucial for understanding solubility, designing chemical processes, and predicting reaction spontaneity.
Tips: Enter both lattice energy and hydration energy values in kJ/mol. The calculator will sum these values to give the Delta H solution.
Q1: What does a negative ΔH_sol indicate?
A: A negative ΔH_sol indicates an exothermic dissolution process where energy is released to the surroundings.
Q2: What does a positive ΔH_sol indicate?
A: A positive ΔH_sol indicates an endothermic dissolution process where energy is absorbed from the surroundings.
Q3: How are lattice and hydration energies determined experimentally?
A: These values are typically determined through calorimetry experiments or calculated using theoretical models based on ionic charges and sizes.
Q4: Does ΔH_sol alone determine solubility?
A: No, while ΔH_sol is important, entropy change (ΔS) also plays a crucial role in determining solubility through the Gibbs free energy equation (ΔG = ΔH - TΔS).
Q5: Are there typical ranges for these values?
A: Lattice energies typically range from 600-4000 kJ/mol, while hydration energies range from -300 to -5000 kJ/mol, depending on the ionic compound.