Kp = Kc (RT)^Δn Equation:
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The Kc to Kp equation converts the concentration-based equilibrium constant (Kc) to the pressure-based equilibrium constant (Kp) for gas-phase reactions. This conversion is essential when dealing with reactions where partial pressures are more relevant than concentrations.
The calculator uses the equation:
Where:
Explanation: The equation accounts for the relationship between concentration and pressure in gas-phase reactions, where Δn represents the difference between moles of gaseous products and reactants.
Details: Accurate Kp calculation is crucial for understanding gas-phase equilibria, predicting reaction directions, and determining the extent of reactions under different pressure conditions.
Tips: Enter Kc value (must be positive), temperature in Kelvin, and Δn value (can be positive, negative, or zero). All values must be valid numerical inputs.
Q1: What is the difference between Kc and Kp?
A: Kc is the equilibrium constant in terms of concentrations, while Kp is in terms of partial pressures. They are related through the ideal gas law.
Q2: When should I use Kp instead of Kc?
A: Use Kp when dealing with gas-phase reactions where pressures are measured or more convenient, especially in industrial applications involving gases.
Q3: What does Δn represent?
A: Δn is the difference between the total moles of gaseous products and the total moles of gaseous reactants (Δn = n_products - n_reactants).
Q4: What are typical values for Kp?
A: Kp values can range from very small (<< 1) for reactant-favored reactions to very large (>> 1) for product-favored reactions, similar to Kc.
Q5: Are there limitations to this equation?
A: This equation assumes ideal gas behavior and is most accurate for reactions where the ideal gas law applies. It may be less accurate at high pressures or temperatures.