Kp = Kc (RT)^Δn Formula:
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The Kc to Kp formula converts equilibrium constants from concentration-based (Kc) to pressure-based (Kp) values for gas-phase reactions. It accounts for the relationship between concentration and partial pressure in ideal gases.
The calculator uses the formula:
Where:
Explanation: The formula converts between concentration-based and pressure-based equilibrium constants using the ideal gas law relationship.
Details: Accurate conversion between Kc and Kp is crucial for analyzing gas-phase equilibria, predicting reaction directions, and understanding pressure effects on chemical systems.
Tips: Enter Kc value, gas constant R (default 0.0821), temperature in Kelvin, and Δn value. All values must be valid numerical inputs.
Q1: When should I use Kp instead of Kc?
A: Use Kp for gas-phase reactions when working with partial pressures instead of concentrations.
Q2: What is the significance of Δn in the formula?
A: Δn represents the change in the number of moles of gas during the reaction and determines the exponent in the conversion formula.
Q3: What are typical values for Kc and Kp?
A: Both are unitless equilibrium constants. Kc > 1 favors products, Kc < 1 favors reactants. The same applies to Kp.
Q4: Are there limitations to this conversion?
A: The formula assumes ideal gas behavior and may not be accurate for real gases at high pressures or low temperatures.
Q5: Can this formula be used for all gas reactions?
A: Yes, for ideal gases. For real gases, additional corrections may be needed based on fugacity coefficients.